MTBE in Naptha Samples

Chromatography Forum: GC Archives: MTBE in Naptha Samples
Top of pagePrevious messageNext messageBottom of pageLink to this message  By Sunil on Monday, July 12, 2004 - 05:11 am:

I am using a 100 metre Petrocol column which is unable to separate 2,3 Dimethylbutane and MTBE in Naptha.The temperature for GC oven starts from 30 deg.c.& the carrier is Helium. I would like to know whether 150 metre DH Petrocol Column separate MTBE from 2,3 dimethylbutane without using cryogenics?


Top of pagePrevious messageNext messageBottom of pageLink to this message  By Gasman on Monday, July 12, 2004 - 06:36 am:

Sunil,

I do not know if the 150 meter column will do the job. However, you should look into the literature, the best method is to inject the napha into a DB-1 type column and then go into the 10 meter Lowox column from Varian (I am not from Varian). The two columns should go either into a valve or a Deans switch system to allow you to backflush any heavies. We have customers who can see 1ppm of MTBE easily in their naptha using this approach.


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