By Jerry G. on Tuesday, August 17, 2004 - 05:56 am:
Any ideas on how to analyze residual pTSA and pTS-Cl in pTS-anydride? I have tried some NP-LC but pTSA does not come off the column and its not volatile enough to use GC. I know I can determine the pTS-Cl by titration and I am currently doing some near-IR experiments as well, but I would like to do it by LC if possible. Any ideas???
Thanks in advance for your input!!
By A.Mouse on Tuesday, August 17, 2004 - 03:39 pm:
SEC with the smallest pore DVB column that you can get. Check at Waters or Polymer Labs!
By Me on Tuesday, August 17, 2004 - 05:07 pm:
To A.Mouse. I think you are completely wrong. Do you have any example of this or similar separation using SEC?
By A.Mouse on Tuesday, August 17, 2004 - 07:14 pm:
Yes. Separation of a styrene monomer from a styrene dimer.
Otherwise, I do not see any way that this could be done with a LC technique. Of course, if somebody else has a better idea, please feel free to post it. Jerry needs it...