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Mobile-Phase Buffers, Part I -- The Interpretation of pH in Partially Aqueous Mobile Phases

What happens to the pH when an organic solvent is added to a buffer?

Keywords: aqueous pH; partially aqueous solutions mobile phase pH; junction potential; autoprotolysis constant; pH scale; buffer pKa; hydrogen ion activity

LC-GC 20(11) 1028-1032 (2002)

G. William Tindall